I made one piece larger and hammered a right angle flange, trimmed the flat edge on the other piece to fit inside it, then folded the flange over a little at a time. The problem is keeping the edges planar so they fit together after hammering the shape. I didn't get it right at first but was able to fold over the flange at the few places that met, then work around the edges to bring the rest in. The curved shape wasn't strong enough to withstand squeezing the pieces together with clamps. I think I used a piece of 1/4" steel upright in the vise for the anvil for outside curves and water pipe for the inside ones.
These days I have temperature controlled soldering irons, a nice one at work and an old Hakko without a readout at home. They are much nicer than uncontrolled ones because they can use a 2X - 3X more powerful heater without burning the tinning off the tip.
Previously I used a soldering gun or a 100W iron for larger jobs where a torch would cause damage, like melting wire insulation. If necessary I preheat the work on a hotplate or with a hot air gun.
The electric iron localizes the heat well enough to control the molten area. Solder changes appearance when it melts, less than steel but more than aluminum when TIG welding.
jsw