How can calculate isotacticity(I.I, mmmm%) of Polybutene-1(PB-1)?

Jun 07, 2006 0 Replies

Hello, everyone



I am in charge of NMR operation. I would like to calculate istactic index of PB-1 samples which are batch-sample and commercial sample. In some patent, they calculated I.I by using integration area of 28ppm ~27.6ppm(27.73 ppm, mmmm) and 5 times integration area of



26.59ppm(mrrm) of PB-1 side chain methylene group.

As I know generally, I.I is calculated by using ratio of mmmm part and other part(mmmr, rmmr,mrrm,....).



What is the difference between both methods.



Please help me.



Thank you.



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