Hello everyone,
Thanks for all the replies. Sorry I've taken a few days to follow up my question. I had a hectic weekend.
I'm also a little puzzled about the mechanism of rusting. Every chemistry book and article I can find on the subject refers to rusting occurring when there is liquid water on the surface of the iron. But I don't think condensation occurs very often in our shed. Sometimes I have been out there at dawn and I've never noticed any condensation as the air temperature rises. So I figure that water vapour in the air must be able to cause rusting. But heating seems to stop the rusting. I have had a piece of machined steel (a part with a broken tap stuck in it) sitting on my desk in the house for the last two years. It hasn't rusted.
Suppose we take some damp air and heat it, but keep the pressure constant. For the pressure to be the same, the water molecules in the warm air collide with my iron object less often, but with greater momentum than the water molecules in the cold air. Maybe this is the key? Water molecules in warm air collide with the iron object less often, so the rate of corrosion is lower. But if that was the case I would expect iron objects in the house to corrode slowly. They do not appear to corrode at all. Are there any chemists here who can provide me with a simple explanation for why heating prevents rusting?
Iggy, thanks very much for the offer of the heating cable. For a while I wondered what it was, because I thought that as the cable length is increased, the resistance and so the power output must fall. But I figure that it must consist of two wires with some kind of resistive material between then. Is that right? I will have a think about the best way to protect this power supply and get back to you. One website publishes a formula for calculating a heater size, and it recommends a wattage which would be unrealistic with 5 W/ft tape. I have seen some hygrostats on eBay, so I might invest in one of those and connect it to a higher wattage heater.
It is a nice power supply. It's built like a tank and built to be maintained. I was lucky to get it actually. Last Monday I stopped by a laboratory which I had helped clear out a couple of weeks before (I took their unwanted gear, some to keep and some for eBay). There was no one there but the power supply was left for the trash. A couple of days later the whole building had been demolished. It's amazing how quick buildings get demolished now.
Best wishes,
Chris