Copper wire is far less likely to give you trouble in the long run, IF it is pulled in carefully without insulation damage. But it's going to cost you a lot more.
You have to go one or two sizes larger with Aluminum to equal the ampacity at a specified voltage drop compared to Copper wire. But the Aluminum wire costs you SO much less, you can bump it an extra size larger and have less problem with lights dimming.
You can go Way Huge if you can get a full roll of surplus 4/0 or250MCM or 350MCM Aluminum wire for cheap, and you place a big enough
4" or 5" conduit for the way huge wire - the problem is, you'll have to use straight-splice or pin conversion lugs to get the huge wires into the normal size breaker lugs and panel lugs at each end.Safety grounds don't need to be mega oversized for voltage drop at your distance - they only need to carry enough fault current to trip the breaker, voltage drop isn't a big dea if the resistance is low enough to do it fast.
Stryped: You mentioned somewhere back in the thread using jacketed wire and going partial direct bury over an obstruction - DON'T. That's going to be the one spot that gives you endless trouble. Someone's going to get overly enthusiastic with a pick or a shovel and cause some serious excitement... And could get hurt in the process.
Do it right - either dig your trench way deep and get the conduit under the obstruction (wall fooring or big tree root), or get a jackhammer and blast a slot in the boulder.
If you have no choice but to go over the obstruction and the conduit is going to be less than 18" dirt cover below finished grade, put a few inches of sand and then a 4" to 6" thick reinforced (welded wire or rebar) protective concrete cap over the conduit - preferably mixed with Red concrete colorant so people figure out "Do Not Dig! Power wires here!"
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