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I agree with Jeff that using the HV probe is a safe way discharge the caps. Also, you probably should buy one on ebay, since that will give you a probe with a proper high-voltage-safe housing and high-voltage- insulated wire. If you are feeling adventurous and have some high voltage wire on hand,
How long "a while" is depends directly on the probe's resistance. For example, if it is fairly low, like 200 megohms, the time constant RC is 2*10^8*10^-6, or 200 seconds. Voltage goes as V0 * e^(-t/RC). At time t+RC, you will have 37% as much voltage as at time t. If you start at V0 = 10000V, it will take 4.6 RC, or about 15 minutes, for the voltage to drop below 100V. If the probe's resistance is reasonably high, ie 1000 to 5000 megohms, the same drop would take 75 to 375 minutes - assuming the capacitor has no leakage.
Finding out whether (or how badly) each capacitor leaks is probably the most important thing to test. If you measure the voltage, then detach the meter, reattach exactly a minute later and remeasure, you can figure out the capacitor's leakage resistance via the equation above: R = t / (C*(log V0 - log V1)). (base e logs)
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I think you should read the high-voltage probe page mentioned above, and also
AIUI, a Franceformer is a neon-sign transformer that delivers AC rather than DC; if so you will need a rectifier. Correct?
If you use line voltage or some other kind of transformer, such as an oil-furnace igniter, you'll need to use a high-voltage resistor in series with it and your rectifier to limit the inflow current when charging a cap. A neon sign transformer probably doesn't need such a resistor.
To avoid damaging terminals with sparks, you might want to attach some
6" wires to each cap, with hooks or loops formed on the wire ends to let you hang a test-leads carrier (fiberglass strip at end of leads) or a shorting bar from a distance.-jiw