I'm designing and building a small 3-stage high pressure compressor for oxygen gas, to make liquid oxygen. It will take the 5 lpm ~95% pure output of an oxygen concentrator, and compress it to ~200 atm, 3000 psi, and then it will be expanded to liquify about 80% of the concentrator output, over three compression/expansion cycles on average. The other 20% will be discarded.
It has three cylinders, 48 mm dia for the first stage cylinder, 22 mm dia second cylinder, 9.2 mm dia third cylinder. The strokes are all 55 mm. The connecting rods go from the crank to pins on drive rods which drive the pistons, rather than directly to gudgeon pins on the pistons.
This can't be lubricated, because it is to be used for oxygen. I can't use plastics, except perhaps graphite loaded PTFE for the lower pressure cylinders, so I'm going with bronze on cast iron for the low friction and wear.
The compressor works at low speed, less than two hundred rpm. This is to minimise the heating of the gas, the adiabatic compression should be as near to reversible as possible in order to improve efficiency, and a faster speed would make the compression irreversible. Actually at that speed significant heat is lost to the walls, making the compression somewhat isothermal, even better. It also minimises the speed of the wearing surfaces.
It's part of the ground support equipment for a small ~100 lb thrust lox/kero turbopumped engine I am developing for model rocketry use.
Anyway. Following a suggestion elsewhere I have polished the insides of the cylinders, which I turned from solid. I wasn't going to use rings, but make the entire piston out of bronze.
Pistons 2 and 3 should run at about 150 C, and will get to that temperature quite quickly. I don't think they are likely to get above 250 C. I don't really mind if they leak a bit on startup, so perhaps slightly undersize at room temperature bronze pistons would do.
A very good gas seal is required once it gets going, there is 3,000 psi on one side of the smallest piston, and atmospheric pressure on the other. However the better seals are only needed on the smaller cylinders, so expansion wouldn't be so much of a problem there.
However, I could make the pistons from cast iron and use bronze rings instead, it would have better thermal expansion properties. I don't think it will be possible to use rings with gaps in them though. This kind of limits me to one ring which is somehow fixed to the cast iron piston, or perhaps two, one on the bottom and one on the top.
Anybody got any better ideas? Comments?
Thanks,