Titanium - Crevice Corrosion

I have a Grade 2 Ti tube (2mm wall) which has been lying in a stainless tank
containing hot orthophosphoric acid.
The contacting face of the tube now exhibits a line of perfectly round pits.
As Ti is pretty resistant to pitting, crevice and galvanic corrosion, does
anyone have any ideas why this had occurred?
Reply to
Dave Herbal
Loading thread data ...
Dave:
It sounds like crevice corrosion. Whether you should have significant corrosion or not depends on some details like the acid concentration and temperature, neither of which you stated.
Timet has some isocorrosion data (5mpy) that you can look up. Go to
formatting link
and download the book in pdf format. Look on page 20 of the Acrobat file for Figure 12. You'd expect 5 mpy for 30% acid at room temperature.
Pittsburgh Pete
DISCLAIMER
We don't believe what we write, and neither should you. Information furnished to you is for topical (external) use only. This information may not be worth any more than either a groundhog turd, or what you paid for it (nothing). The author may not even have been either sane or sober when he wrote it down. Don't worry, be happy.
Reply to
Pittsburgh Pete
in article snipped-for-privacy@posting.google.com, Pittsburgh Pete at snipped-for-privacy@hotmail.com wrote on 28/10/03 2:17 pm:
Cheers for that Pete.
What i have are perfectly round pits, like that seen in Fig. 18, so i am wondering now if the Ti tube has been rubbing on the stainless and lost it's protective coating? Hmmm. More examination of the job, I think.
Reply to
Dave Herbal

PolyTech Forum website is not affiliated with any of the manufacturers or service providers discussed here. All logos and trade names are the property of their respective owners.