Last thing first- These are portable electropolishers.
All they are is a transformer- The output is 40 volts, at about 2 or 3 amps. A battery charger will work, but will be much slower, due to the lower voltage.
You use a spring ground clamp for the ground, on the work, close to where you are polishing.
You use a "wand" for the positive- I made mine from a scrap piece of
5/8" round silcon bronze, but some of the commercial units just use flattened 1/2" copper pipe. The trick is to wrap the business end of the wand with something tough, but soft- I use 2" wide woven fiberglas tape. I wrap a few wraps on, and tape it on with black electrical tape.
Then dip in your mild phosphoric acid or Citri-Surf liquid. You dont want the metal of the wand to touch the stainless, you want the electricity to conduct thru the wet fiberglas tape.
the fiberglas will burn and char after a while, and need to be removed, tossed, and replaced with new.
Works great for removing weld discoloration. Not so good at removing blackened stainless that has been forged- for that, I have to send it out to a commercial house that uses a 100 volt power supply that is as big as a refridgerator. And commercially, they find it helps to dip the piece in a bathtub of phosphoric, which they heat to 120 degrees or so.