I just had to do this several times a few months ago. I cleaned the valve and pipe well with a wire brush made for the job, used plenty of flux, and heated the joint quickly. I use an air/acetylene torch for plumbing work because it's so fast. Make sure the torch you use is big enough for the job. Heating the joint fast and getting the solder in quickly gives the heat less time to travel to the rest of the valve. The brass that the valve is made of transmits heat much slower than pure copper so this is why fast heating is best. ERS