I haven't kept up with current books about Python (a long time ago I bought a CORBA-via-Python book, which turned out not useful, and an overly elementary Python book) and have used online refs since to deal with particular questions. However, I've seen both of the following books recommended in comp.lang.python : "Python Standard Library", Fredrik Lundh, and "Python Cookbook, Second Edition", Martelli/Ravenscroft/Ascher, . Both are a few years old now and I don't know if newer versions are out.
My thought is that it isn't worthwhile to get a book about Python syntax, which can be presented well enough online. However, the Standard Library book should be able to present background and framework information that online man pages often lack, while the Cookbook presents numerous segments of code for specific purposes, which may be useful examples for learning Python. The tables of contents of both books are available at those O'Reilly links, so you may be able to see if one or the other matches up with what you want.
Also the books "Dive Into Python" and "How To Think Like A Computer Scientist" are online somewhere, and mailing list may help.
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