Gold-magnesium alloys. R. Vogel. Z. anorg. Chem., 1909, 63, 169-183. In: ? The Journal of the Society of Chemical Industry. 28 [10] 1041. October 15, 1909.
An extract.
In order to prepare the alloys, the magnesium was melted, and gold sheet added as necessary. The union was always accompanied by a very large evolution of heat, in some cases almost to explosiveness. The same characteristic occurs in the alloy of gold with zinc and cadmium, and indeed forms a series in accordance falling atomic weight. The miscibility of the gold with magnesium in the solid state, with the formation of mixed crystals, is up to 3 per cent., and with zinc and cadmium up to 5 per cent.
---- The late Alexander P. Hardt, Incendiary Potential of Exothermic Intermetallic Reactions, Lockheed Palo Alto Research Laboratory Report LMSC-D177523,
1971. Discusses a number of intermetallic reactions, none however, using Au.Accepting carbon and silicon as metallic surprisingly high temperatures are possible:
TiB2 3770o C TiC 3600 ZrC 3800 NbSi2 3300 HfC 4200
I remain curious as to the source of the heat!