Bill
Surface finish is measured in micro inches on an RMS, RA, or other weighting scale.
One of my projects required the wetted area on part of a heat exchanger to be electro-polished to 25 micro inches RMS or better. We called in competitive bids from firms doing this for a living.
Here is what we were told: Electro polishing DOES NOT improve the micro inch finish of the surface; If you require a 25 RMS finish after electro polishing you have to start with a 25 RMS mechanical finish to begin with.
Electro polishing changes the nature of the surface finish, but does not produce a measurable change in RMS finish.
In my business the electro polish reduced the particulate retention... a most desirable feature in my application.
In your business it may reduce surface friction or improve product finish... my guess.
But, electro polishing will not improve the finish from, say 125 micro inches to 32, 25, or 16 micro inches, unless the E-P process has changed drastically in the last 10 years or so, in which case I defer to newer experience.
As to how to do it. Try googling; I don't recall it being a particularly exotic process. We just didn't want to deal with the mess and disposal of chemicals, hence the subcontract.
Wolfgang