Any Chemists on forum? Hypo

Oct 27, 2013 4 Replies

Sodium Thriosulphate (or hypo) is (was?) used as a photographic 'fixer' for black & white photographs.



It also has a useful reaction with steel producing an intense black colour on the surface of the steel. Diluted hypo, warmed to 75 deg C, and ultra cleaned steel swirled about in it produce this reaction in about a minute. Useful for blacking tools and the like.



But what is the reaction ? Is this a deposit (so maybe transient) or is there a reaction with the atoms on the surface of the steel (so hopefully reasonably well bonded)?



I know that it works but what is happening, anyone know?



AWEM



I suspect the black colour is iron sulphide, but I have no idea how well bonded or permanent it is. Incidentally there is no R in thiosulphate.

Cliff Coggin.

10 sec Google shoed this:
formatting link

sent before I was ready ... or this:

formatting link

Join the Discussion

Have something to add? Share your thoughts — no account required.

Didn't find your answer?

Ask the community — no account required