I've been using the vertex chamfer to put a 3 sided chamfer in the inside corner of pockets. I've noticed that if the pocket is created by extruding a sketch (whether a boss, or a cut), there seems to be a limitation as to the size of the chamfer. It has nothing to do with running past the edge of the part.
For example, extrude block 10" on a side, 2" thick. On the top of this extrude a boss 6" on a side, 2" thick. Next, put an extruded cut 3" on a side on one corner of the boss, down to the top of the 10" extrusion. Now put a vertex chamfer in the resulting corner. The largest size that will work is .471" and change. Why?
I haven't been able to figure out the limiting factor(s). Has anyone else seen this problem? The only workaround that I've found is to create sketches, planes, etc. and put an extrusion in the corner. Since parts may have dozens of these corner, that is a real time consuming project.