My experience was that my decades of soldering experience made learning to weld harder: I was accustomed to being able to rely on the base metal not melting, and seeing the solder melt meaning I was pretty much done -- and if I did'nt like the result, I could start over. I found getting used to the idea that I was working as much with the melted base metal as with the filler, and that there was no going back (you can rework a weld, but it isn't like doing the first weld over again!) to be very, very different.
I strongly endorse learning to weld in a class, or at least with the help of an expert who has lots of time and patience to help you improve.